In 1759, Italian geologist Giovanni Arduino (1714-1795) dated a letter to Professor A.Vallisneri the younger, in which Arduino proposed a classification of Earth's surface rocks according to four brackets of successively younger orders: Primary, Secondary, Tertiary and Quaternary. These are the four geological eras used today.
The volcanic rocks without fossils which he saw in the Atesine Alps that formed the cores of large mountains he called Primary. Overlying them, the fossil rich rocks of limestone and clay that were found on the prealpine flanks of the mountains he called Secondary. The less consolidated fossil-bearing rocks of the subalpine foothills, he named Tertiary, and the alluvial rock deposits in the plains were the Quaternary. link.